2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene]
نویسندگان
چکیده
In the title compound, C15H10Br2, each mol-ecule is situated on special postion mm, so the asymmetric unit contains one-quater of a mol-ecule. The 2,7-di-bromo-9H-fluorene fragment and three spiro-cyclo-propane C atoms lie on different planes, which are perpendicular to each other. In the crystal, π-π inter-actions between aromatic rings [inter-centroid distance = 3.699 (3) Å] pack the mol-ecules into stacks extending in [001].
منابع مشابه
Separation of xylenes by enclathration.
The isomers of xylene have been separated by enclathration using three host compounds: 9,9'-bianthryl (H1), 9,9'-spirobifluorene (H2) and trans-2,3-dibenzoylspiro[cyclopropane-1,9-fluorene] (H3). The structures of each host with a single xylene isomer have been elucidated and, for H1, the relative lattice energies of the clathrates with ortho- and para-xylene have been evaluated.
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